As Chile is the host nation of Copa America, they will definitely strive to go well especially on the early stages. Ecuador is a very good opponent for hosters to start their win line. Chile has a lot of good players, who even are in european football teams. Ecuador will play without their 2 main players that decreases their chances badly.
In their last 6 meetings Chile always won , the only time Ecuador managed to score a goal and it was done by the player that will be absent in the upcoming match.
So home win for Chile
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